Photochromism in single nitrogen-vacancy defect in diamond

Single nitrogen vacancy centers in chemical vapor deposited diamond nanocrystals.

Nanodiamond crystals containing single color centers have been grown by chemical vapor deposition (CVD). The fluorescence from individual crystallites was directly correlated with crystallite size using a combined atomic force and scanning confocal fluorescence microscope. Under the conditions employed, the optimal size for single optically active nitrogen-vacancy (NV) center incorporation was ...

Photophysics of single nitrogen-vacancy centers in diamond nanocrystals

Single-Qubit Operations with the Nitrogen-Vacancy Center in Diamond

A concept combining optics and microwave pulses with the negative charge-state of the nitrogenvacancy (NV– ) center in diamond is demonstrated through experiments that are equivalent to single-qubit gates, and decoherence for this qubit is examined. The spin levels of the ground state provide the two-level system. Optical excitation provides polarization of these states. The polarized state is ...

Resolving single molecule structures with Nitrogen-vacancy centers in diamond

We present theoretical proposals for two-dimensional nuclear magnetic resonance spectroscopy protocols based on Nitrogen-vacancy (NV) centers in diamond that are strongly coupled to the target nuclei. Continuous microwave and radio-frequency driving fields together with magnetic field gradients achieve Hartmann-Hahn resonances between NV spin sensor and selected nuclei for control of nuclear sp...

Jahn-Teller-induced femtosecond electronic depolarization dynamics of the nitrogen-vacancy defect in diamond

Single-photon emission from the nitrogen-vacancy defect in diamond constitutes one of its many proposed applications. Owing to its doubly degenerate 3E electronic excited state, photons from this defect can be emitted by two optical transitions with perpendicular polarization. Previous measurements have indicated that orbital-selective photoexcitation does not, however, yield photoluminescence ...